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The kagome metals 𝐴⁢V₃⁢Sb₅ (𝐴=K, Rb, Cs) exhibit a complex interplay between charge density wave (CDW) order and superconductivity. Here, in this study, we use ultrafast coherent phonon spectroscopy to probe the evolution of CDW order in hole-doped CsV₃⁢Sb_5−𝑥⁢Sn_𝑥 across a broad range of compositions (0 ≤ 𝑥 ≤ 0.68). While thermodynamic and diffraction measurements show long-range CDW order vanishes above 𝑥 ≈ 0.05, we observe persistent signatures of CDW fluctuations up to the highest doping levels, with correlation times on the order of several picoseconds. These results indicate the presence of a robust fluctuating charge order that survives wellmore » beyond the established CDW phase boundary. Furthermore, these fluctuations are enhanced near a doping-tuned quantum phase transition at 𝑥* ≈ 0.15, which coincides with a local minimum in the superconducting 𝑇_c double-dome. Additional measurements on Ti- and K-substituted samples confirm that this behavior is intrinsic to hole doping and not tied to disorder. Overall, our findings suggest that CDW fluctuations play a central role in the electronic phase diagram of 𝐴⁢V₃⁢Sb₅ and may mediate or compete with superconductivity.« less

The class of AV₃Sb₅ (A=K, Rb, Cs) kagome metals hosts unconventional charge density wave states seemingly intertwined with their low temperature superconducting phases. The nature of the coupling between these two states and the potential presence of nearby, competing charge instabilities however remain open questions. This phenomenology is strikingly highlighted by the formation of two ‘domes’ in the superconducting transition temperature upon hole-doping CsV₃Sb₅. Here we track the evolution of charge correlations upon the suppression of long-range charge density wave order in the first dome and into the second of the hole-doped kagome superconductor CsV₃Sb_5–xSn_x. Initially, hole-doping drives interlayer chargemore » correlations to become short-ranged with their periodicity diminished along the interlayer direction. Beyond the peak of the first superconducting dome, the parent charge density wave state vanishes and incommensurate, quasi-1D charge correlations are stabilized in its place. These competing, unidirectional charge correlations demonstrate an inherent electronic rotational symmetry breaking in CsV₃Sb₅, and reveal a complex landscape of charge correlations within its electronic phase diagram. Our data suggest an inherent 2k_ƒ charge instability and competing charge orders in the AV₃Sb₅ class of kagome superconductors.« less